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Lithopone’s historical significance is further accentuated by the advancements and modifications that followed its inception. The 1874 patent by J.B. Orr, for instance, ushered in a new white pigment—Orr’s Zinc White. This innovation was attained by co-precipitating zinc sulfate and barium sulfide, followed by a calcination process. Further refinements marked the subsequent decades, the most notable being the enhancement of lightfastness achieved in the 1920s by introducing small amounts of cobalt salts before calcination.

Titanium Dioxide (TiO2) is a widely used white pigment that possesses excellent properties such as high whiteness, strong hiding power, and chemical stability. It is commonly used in various applications, including paints, plastics, coatings, and paper industries. In this article, we will discuss the top TiO2 white manufacturers in the world. Navigating the Landscape of Titanium Dioxide Manufacturers A Focus on Best Pigment Rutile Producers